در مورد ABS، بیش تر بدانید
اکریلونیتریل بوتادین استایرن، که به اختصار ABS نامیده می شود، یک ترموپلاستیک مهندسی مات است که دارای خواص مطلوبی چون مقاومت در برابر ضربه، مقاومت در برابر مواد شیمیایی، فرایند پذیری مناسب و … می باشد و به طور گسترده ای در قطعات الکترونیکی، صنایع لوازم خانگی، خودروسازی، لوازم پزشکی و … کاربرد وسیعی دارد.
در این مقاله قصد داریم به معرفی پلیمر ABS بپردازیم تا با مشخصات و ویژگی ها و کاربردهای آن در صنایع گوناگون بیشتر آشنا شوید.
ABS چیست؟
ABS یک پلیمر ترموپلاستیک مهندسی مقاوم در برابر ضربه و آمورف است. ABS از سه مونومر ساخته شده است: اکریلونیتریل ، بوتادین و استایرن:
- اکریلونیتریل: مونومری است که از پروپیلن و آمونیاک تولید می شود. این جزء به مقاومت شیمیایی ABS و پایداری حرارتی کمک می کند.
- بوتادین: به عنوان محصول جانبی تولید اتیلن از شکست حرارتی با بخار تولید می شود. این جزء چقرمگی و مقاومت ضربه را به پلیمر ABS می رساند.
- استایرن: طی فرآیند هیدروژن زدایی اتیل بنزن تولید می شود. استایرن سفتی و قابلیت فرآیندپذیری پلاستیک ABS را فراهم می کند.
ABS ترپلیمری است که از پلیمریزاسیون استایرن و اکریلونیتریل در حضور پلی بوتادین تولید می شود. این نسبت می تواند از 15٪ تا 35٪ اکریلونیتریل ، 5٪ تا 30٪ بوتادین و 40٪ تا 60٪ استایرن متفاوت باشد.
تاریخچه ABS
کوپلیمرهای استایرن آکریلونیتریل از دهه 1940 در دسترس بوده و به دلیل چقرمگی بهتر نسبت به استایرن سبب شده که برای بسیاری از کاربردها مناسب باشد، اما محدودیت های آن منجر به معرفی یک لاستیک (بوتادین) به عنوان مونومر سوم شد و از این رو طیف وسیعی از مواد به عنوان پلاستیک ABS در دهه 1950 تولید شدند. گستردگی این کوپلیمرها و سهولت فرآیند، ABS را به یکی از محبوب ترین پلیمر های مهندسی تبدیل کرده است.
خصوصیات اصلی ABS
ABS به دلیل داشتن چندین ویژگی فیزیکی از جمله موارد زیر به ماده ای ایده آل برای کاربردهای مختلف تبدیل شده است:
- سختی زیاد
- مقاومت خوب در برابر ضربه، حتی در دمای پایین
- خاصیت عایق الکتریکی خوب
- مقاومت در برابر سایش و فشار
- پایداری ابعادی بالا (از نظر مکانیکی قوی و پایدار در طول زمان)
- براقیت بالای سطح و رنگ پذیری مناسب
ABS خواص مکانیکی بسیار خوبی از خود نشان می دهد، یعنی از نظر ماهیت سخت و چقرمه است و در نتیجه مقاومت خوبی در برابر ضربه ایجاد می کند. اکریلونیتریل بوتادین استایرن درجه بالایی از کیفیت سطح را ارائه می دهد. جدا از این ویژگی ها، اکریلونیتریل بوتادین استایرن از ویژگی های عایق الکتریکی خوبی برخوردار است.
گرید های موجود
ABS با مواد افزودنی و با تغییر نسبت سه مونومر اکریلونیتریل ، بوتادین و استایرن اصلاح می شود. از این رو گریدهای موجود شامل: مقاومت ضربه زیاد و متوسط، مقاومت حرارتی بالا و قابلیت آبکاری فلز هستند. الیاف تقویت کننده برای افزایش سختی و پایداری ابعاد استفاده می شود. ABS به راحتی با سایر پلیمرها مخلوط یا آلیاژ می گردد و دامنه خواص موجود را بیشتر می کند. بازدارندگی در برابر آتش با افزودنی های ضد حریق یا با ترکیب با PVC حاصل می شود.
ترپلیمر اکریلونیتریل- بوتادین- استایرن ( Styrene Butadiene Acrylonitrile ) در گرید های متنوع تزریق عمومی، اکستروژن و ورق، مقاوم به ضربه، مقاوم به حرارت، مقاوم در برابر شعله (خود خاموش شونده)، آنتی استاتیک و… تولید می گردند. این پلیمر دارای خواص مطلوبی چون مقاومت در برابر ضربه، مقاومت در برابر مواد شیمیایی، فرایند پذیری مناسب و … می باشد و پس از عملیات قالب گیری یا اکستروژن نیز از پایداری ابعادی و براقیت سطحی مناسبی برخوردار است که در صنایع لوازم خانگی، خودروسازی، صنایع الکتریکی، لوازم پزشکی و … کاربرد وسیعی دارد.
کاربردهای ABS
ABS به دلیل تعادل خوب خواص، چقرمگی، مقاومت در برابر ضربه و دما و همچنین سهولت قالب گیری و کیفیت بالای سطح، کاربردهای بسیار گسترده ای دارد. این وسایل شامل لوازم خانگی، قطعات داخلی گوشی تلفن و سایر وسایل دفاتر اداری، کلاه ایمنی، بدنه چمدان، لوله ها و اتصالات است.
-
ABS در چاپ سه بعدی
امروزه ABS یکی از متنوع ترین مواد موجود برای چاپ سه بعدی است. ABS به صورت رشته های (فیلامنت) بلند پیچیده شده به دور قرقره وجود دارد. فرآیند چاپ سه بعدی که با ABS استفاده می شود، فرآیند FDM (Deposition modelling Fusion) است که در آن مواد از طریق یک نازل ظریف گرم و فشرده می شوند تا طرح شما در لایه های 250 میکرونی ساخته شود.
اشیای چاپ شده با ABS دارای استحکام، انعطاف پذیری و دوام کمی بالاتر هستند. این یک ماده عالی برای نمونه سازی است و می توان آن را به راحتی ماشین کاری، سنباده، چسب و رنگ کرد.
یکی از اصلی ترین رقبای چاپ سه بعدیABS ، PLA است. برخلافABS ، PLA یک پلاستیک تجدید پذیر است. بنابراین زیست تخریب پذیر است در حالی که ABS فقط زیست سازگار است. با این حال، مانند بسیاری از مواد پلاستیکی، قابل بازیافت است.
-
خودرو
قطعات اتومبیل الزامات خاصی را به خصوص در مواد استفاده شده ایجاد می کند. تحت فشارهای شدید، آنها باید از نظر ابعادی پایدار باشند و نباید تغییر شکل دهند، حتی اگر با تغییرات دمایی زیادی روبرو شوند.
-
برق و الکترونیک (E&E)
صنایع برق و الکترونیک به سطوحی نیاز دارند که نه تنها در برابر خراش و سایش بسیار مقاوم باشند بلکه تزئینی بوده و نگهداری آنها آسان باشد. عملکرد آنتی استاتیک عالی ABS در اینجا یک مزیت خاص است.
-
تجهیزات اداری
محصولات جذاب با طراحی ظریف و کیفیت بالا احساس رفاه در خانه و محل کار را ایجاد می کنند. ABS می تواند طرح های رنگی هیجان انگیز و متنوعی ایجاد کند. گرید ها را می توان آبکاری، مهر برجسته یا فلزی نیز کرد. سطوح می توانند مات یا براق باشند.
بازیافت و سمیت
همانطور که در بالا ذکر شد پلاستیک ABS ماده زیست سازگار و قابل بازیافت است. ABS شماره پلاستیکی خاص خود را ندارد. محصولات ساخته شده با ABS از شماره بازیافت شماره 9 استفاده می کنند.
○ 100% قابل بازیافت است.
○ غیر سمی و بی ضرر است.
هیچ ماده سرطان زایی شناخته شده ای ندارد و هیچ اثر سوء بر سلامتی مرتبط با قرار گرفتن در معرض آن شناخته نشده است.
ABS بازیافت شده را می توان با مواد خام مخلوط کرد و ضمن حفظ کیفیت بالا محصولاتی با هزینه کمتر تولید کرد.
تولیدکنندگان اصلیABS
عبارتند از: : Ineos ، LG Chem ، RTP Company ، SABIC
شرکت های پتروشیمی داخلی نیز از قبیل پتروشیمی تبریز، پتروشیمی قائدبصیر تولیدکننده این ماده پلیمری هستند. همچنین پتروشیمی قائد بصیر تنها تولید کننده گرید های رنگی این ماده پلیمری در ایران و بر اساس سفارش مشتری می باشد. گرید 50N پتروشیمی یک محصول پرکاربرد در صنعت ایران و کاربردهای عمومی است.
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شرکت علمی سازان پاسارگاد با برند کانگورو تامین کننده و وارد کننده مواد اولیه شیمیایی و پلیمری، اقدام به تامین گسنرده ماده پلیمری ABS نموده است، جهت کسب اطلاعات بیشتر و یا سفارش گذاری با شماره 88064800 تماس حاصل نمایید، همکاران ما آماده ثبت سفارشات شما هستند.
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